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If you click Subscribe, the game will (eventually) download it. You can try deleting the mod cache (the file Civ5ModsDatabase.db in My Documents\My Games\Sid Meier's Civilization 5\cache\) to see if you can jump-start the process. Most people find the game often re-downloads all your mods for no good reason.
In any case, you can download it manually here [forums.civfanatics.com].