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Star Wars: Knights of the Old Republic AKA KOTOR

Best if used with Mouse Look turned off with default control setup. Easy controls, dont even need to use the thumbsticks if you just access everything with the Toggle UI or entering the menu.

guide - Launch Steam Big-Picture 
start - Menu 
a - Defaul Action 
b - Remove action 
x - Switch Character 
y - Pause 
Left Stick - Movement (change z/c to a/d)
Right Stick - Mouse Look 
L1 - Toggle UI 
R1 - Mouse Left Click 
L2 - Quick Save 
R2 - Medpac 
Left Click - Map 
Right Click - Character
D-Down - 3rd option dialog 
D-Right - 2nd option dialog 
D-Left - 4th option dialog 
D-Up - 1st option dialog