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@TipToeInDaSnow
Remember that Wesker is pure evil. He likes to toy with his victims and watch them suffer. Destroying the heart is an assured death, as well as with the head / brain, but slower and more painful. That's why. You got your answer

I feel going for the heart wouldn't be fast enough. Maybe a large caliber round to the brain.

The most lethal attack of Albert Wesker can kill you instantly,ripping apart the heart